Pensum/l?ringskrav

Fra boken "Physical Chemistry" av Laidler, Meiser & Sanctuary (4. utg.) (190 sider)

Kap. 1. The Nature of Physical Chemistry .... (19 sider)

1.3. Systems, States, and Equilibrium

1.4. Thermal Equilibrium

1.5. Pressure and Boyle’s Law

1.6. Gay-Lussac’s (Charles’s) Law

1.7. The Ideal Gas Thermometer (kursorisk)

1.8. The Equation of State for an Ideal Gas

1.9. kun “Dalton’s law of Partial Pressures” t.o.m. eq 1.54

1.12. Real Gases

1.13. Equations of State

1.14. The Virial Equation

Kap. 2. The First Law of Thermodynamics (34 sider)

2.2. States and State Functions

2.3. Equilibrium States and Reversibility

2.4. Energy, Heat, and Work

2.5. Thermochemistry

2.6. Ideal Gas Relationships

2.7. Real Gases

Kap. 3. The Second and Third Laws of Thermodynamics (39 sider) Sidene 94-95

3.1. The Carnot Cycle ( “Carnot’s Theorem” utg?r, “The Thermodynamic Temperature scale” leses kursorisk)

3.2. Irreversible Prosesses

3.3. Molecular Interpretation of Entropy

3.4. The Calculation of Entropy Changes

3.5. The Third Law of Thermodynamics

3.6. Conditions for Equilibrium

3.7. The Gibbs Energy

3.8. kun sidene 127 - 132 . Avsnittet ”Fugacity and Activity” g?r ut.

3.9. The Gibbs-Helmholtz Equation

3.10. Bare avsnittet “Chemical Conversion”

Kap. 4. Chemical Equilibrium (21 sider)

Sidene 151-152

4.1. Chemical Equilibrium Involving Ideal Gases

4.3. Chemical Equilibrium in Solution

4.4. Heterogeneous Equilibrium

4.5. Tests for Chemical Equilibrium

4.6. Shifts of Equilibrium at Constant Temperature

4.7. Coupling of Reactions

4.8. Temperature Dependence of Equilibrium Constants

Kap. 5. Phases and Solutions (35 sider)

5.1. Phase Recognition

5.2. Vaporization and Vapor Pressure (Hildebrands og Crafts regler mindre viktig).

5.3. Classification of Transitions in Single-Component Systems

5.4. Ideal Solutions: Raoult’s and Henry’s Laws

5.5. Partial Molar Quantities

5.6. The Chemical Potential

5.7. Thermodynamics of Solutions

5.8. The Colligative Properties. Avsnittet om “Ideal Solubility and the Freezing Point Depression” g?r ut.

Kap. 6. Phase Equilibria (21 sider)

6.1. Equilibrium Between Phases

6.2. One-Component Systems

6.3. Binary Systems Involving Vapour

6.4. Condensed Binary Systems

6.5. Thermal Analysis

Kap. 7. Solutions of Electrolytes (8 sider)

7.8. Thermodynamics of Ions

7.10. Activity Coefficients (Utledningen av Debye-Hückels grenselov g?r ut; selve loven er pensum).

7.11. Ionic Equilibria

Kap. 17. The Liquid State (13 sider)

17.1. Liquids Compared with Dense Gases

17.3. Intermolecular Forces

17.6. The Hydrophobic Effect

Fra boken "Quantitative Chemical Analysis" av Harris (6. utg.) (105 sider)

Kap. 0. The Analytical Process – hele: 9 s (egenstudium).

0-1. The analytical chemist`s job

0-2. General steps in a chemical analysis

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Kap. 1. Measurements – hele: 11 s , kursorisk

1-1. SI units

1-2 Chemical concentrations

1-3 Preparing solutions

1-4 Solutions and stoichimetry

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Kap. 2. Tools of the Trade – hele: 20 s (2.10 og 2.11 – 4 s - er introduksjon til Excel ) kursorisk

2-1. Safe, ethical handling of chemicals and waste

2-2. The lab notebook

2-3. Analytical balance

2-4. Burets

2-5. Volumetric flasks

2-6. Pipets and syringes

2-7. Filtration

2-8. Drying

2-9. Calibration of volumetric glassware

2-10. Introduction to Microsoft Excel

2-11. Graphing with Microsoft Excel

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Kap. 3. Experimental Error – hele: 14 s

3-1. Significant errors

3-2. Significant errors in arithmetic

3-3. Significant figures and graphs

3-4. Types of error

3-5. Propagation of uncertainty

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Kap. 4. Statistics and Spreadsheets – hele: 15 s

4-1. Gaussian distribution

4-2. Confidence intervals

4-3. Comparison of means with Student`s t

4-4. Comparison of standard deviation with the F test

4-5. t test with a spreadsheet

4-6. Q test for bad data

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Kap. 5. Calibration Methods - 10 s

5-1. Finding the “best” straight line, kun side 81.

5-2. Calibration curves

5-3. Standard addition

5-4. Internal standards

5-5. A spreadsheet for least squares

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Kap. 7. Let the Titrations Begin – 4 sider

7-1. Titrations

7-2. Kun s. 132-133. Kjeldahl analyse

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Kap. 14. Fundamentals of electrochemistry- 24 sider

14.1 Basic Concepts

14.2 Galvanic Cells

14.3 Standard Potentials

14.4 Nernst Equation

14.5 Eo and the Equilibrium Constant

14.6 Cells as Chemical Probes

14.7 Biochemists Use Eo’

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Kap. 15 Electrodes and Potensiometry - 24 sider

15-1. Reference electrodes (unntatt box 15-1)

15-2. Indicator electrodes

15-3. What is a junction potential?

15-4. How ion-selective electrodes work

15-5. pH measurements with a glass electrode

15-6. Ion-selective electrodes

15-7. Using ion-selective electrodes

15-8. Solid-state chemical sensors (kursorisk)

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Kap. 16. Redox titrations – 2 sider

16-1. The shape of a Redox Titration Curve s. 347-349 (ikke tabell)

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Kap. 17. Electroanalytical techniques - 2 sider

17-6. Karl Fischer Titration of H2O. (397-399)

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Kap. 29. Quality Assurance – control charts:

s 733-734: 1 s

Egenprodusert:

Viktige begreper i analytisk kjemi (6 sider, men noe overlapp med kap. 0 i Harris)

Laboratorie?velser i KJM1040 ca. 50 sider

Publisert 25. okt. 2004 22:51 - Sist endret 26. okt. 2004 18:01